The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties.

نویسندگان

  • Daopeng Zhang
  • Yongzhong Bian
  • Jie Qin
  • Ping Wang
  • Xia Chen
چکیده

Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)-Fe(III) centers and the interesting metamagnetic behavior at about 5.0 K resulted from the intermolecular π-π interaction.

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عنوان ژورنال:
  • Dalton transactions

دوره 43 3  شماره 

صفحات  -

تاریخ انتشار 2014